MATERIAL SAFETY DATA SHEET
Section 1 - Product and Company Information
Product Name: 4-tert-Butylphenol
Synonyms: p-tert-Butylphenol; 4-t-Butylphenol; 4-(1,1-Dimethylethyl)phenol; 1-Hydroxy-4-tert-butylbenzene; PTBP.
Molecular Formula: C10H14O
United Chemical Products Ltd. Corp.
Tel: +7 (812) 336-43-99
Fax: +7 (812) 495-97-38
Section 2 - Composition/Information on Ingredients
Product Name: 4-tert-Butylphenol
CAS No.: 98-54-4
Section 3 - Hazards Identification
Appearance: white to almost white solid.
Warning! Causes eye, skin, and respiratory tract irritation. May cause allergic respiratory and skin reaction. Hygroscopic (absorbs moisture from the air).
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye: Causes severe eye irritation.
Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: Causes respiratory tract irritation. In rare instances, exposure may cause sensitization, resulting in inflammation of the mucous membranes and in eczematous eruptions.
Chronic: Repeated or prolonged exposure may cause allergic reactions in sensitive individuals.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: 113 deg C ( 235.40 deg F)
Autoignition Temperature: 510 deg C ( 950.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
OSHA - Final PELs
OSHA Vacated PELs: 4-tert-Butylphenol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - Physical/Chemical Properties
Physical State: Solid
Appearance: white to almost white
Odor: None reported.
pH: Not available.
Vapor Pressure: 13 hPa @ 115 C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 236 - 238 deg C @ 760.00mm Hg
Freezing/Melting Point:96 - 100 deg C
Decomposition Temperature:Not available.
Solubility: soluble in alcohol and ether
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Incompatible materials, dust generation, moisture, excess heat.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
CAS# 98-54-4: SJ8925000
Draize test, rabbit, eye: 10 mg Severe;
Draize test, rabbit, eye: 50 ug/24H Severe;
Draize test, rabbit, skin: 500 mg/4H Mild;
Draize test, rabbit, skin: 500 mg/24H Mild;
Oral, mouse: LD50 = 1030 mg/kg;
Oral, rat: LD50 = 3250 uL/kg;
Skin, rabbit: LD50 = 2520 uL/kg;
CAS# 98-54-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: Oral, hamster: TDLo = 252 gm/kg/20W-C (Tumorigenic - neoplastic by RTECS criteria - Gastrointestinal - tumors).
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Section 12 - Ecological Information
Ecotoxicity: Fish: Fathead Minnow: LC50 = 5.1 mg/L; 96 Hr; Unspecified
Water flea Daphnia: EC50 = 4.2 mg/L; 24 Hr; Unspecified
Bacteria: Phytobacterium phosphoreum: EC50 = 0.21 mg/L; 5 min; Microtox test
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
TOXIC SOLIDS, ORGANIC, N.O.S.
TOXIC SOLID ORGANIC NOS (4-TERT-BUTYLPHENOL)
Section 15 - Regulatory Information
CAS# 98-54-4 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
None of the chemicals in this product are considered highly hazardous by OSHA.
CAS# 98-54-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitization by inhalation and skin contact.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water.
WGK (Water Danger/Protection)
CAS# 98-54-4: 2
Canada - DSL/NDSL
CAS# 98-54-4 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 98-54-4 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Other Information
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall NOVOKUIBYSHEVSK / United Chemical Products Ltd. Corp. be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if NOVOKUIBYSHEVSK / United Chemical Products Ltd. have been advised the possibility of such damages.
document revision date: Tue Nov 13 15:59:38 CET 2012